trans-4-(2-Amino-5-bromo-6-methylpyrimidin-4-ylamino)-1-methylcyclohexanol

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trans-4-(2-Amino-5-bromo-6-methyl­pyrimidin-4-ylamino)-1-methyl­cyclo­hexa­nol

The title compound, C(12)H(19)BrN(4)O, represents the minor component of the two products obtained in a series of transformations involving the Grignard reaction of tert-butoxy-carbonyl-protected 4-amino-cyclo-hexa-none with MeMgBr, and subsequent inter-action of the obtained amino-substituted cyclo-hexa-nol with 4-chloro-6-methyl-pyrimidin-2-amine followed by bromination with N-bromo-succinimi...

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N-(4-amino-1-(1-(4-amino-1-oxo-1-(3,12,23-tris(2-aminoethyl)- 20-(1-hydroxyethyl)-6,9-diisobutyl-2,5,8,11,14,19,22-heptaoxo- 1,4,7,10,13,18-hexaazacyclotricosan-15-ylamino)butan-2-ylamino)- 3-hydroxybutan-2-ylamino)-1-oxobutan-2-yl)-N,5-dimethylheptanamide

Systematic (IUPAC) name N-(4-amino-1-(1-(4-amino-1-oxo-1-(3,12,23-tris(2-aminoethyl)20-(1-hydroxyethyl)-6,9-diisobutyl-2,5,8,11,14,19,22-heptaoxo1,4,7,10,13,18-hexaazacyclotricosan-15-ylamino)butan-2-ylamino)3-hydroxybutan-2-ylamino)-1-oxobutan-2-yl)-N,5-dimethylheptanamide Identifiers CAS number 1264-72-8 [1] ATC code A07 AA10 [2] J01 XB01 [3] QJ51 XB01 [4] PubChem CID 5311054 [5] DrugBank APR...

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4-{2-[(5-Bromo-2-hydroxy­benzyl­idene)amino]eth­yl}benzene­sulfonamide

In the title compound, C(15)H(15)BrN(2)O(3)S, the dihedral angle between the benzene rings is 6.1 (2)° and an intra-molecular O-H⋯N hydrogen bond helps to establish the conformation. In the crystal structure, the mol-ecules are linked by way of N-H⋯O and C-H⋯O hydrogen bonds.

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(E)-4-Amino-N′-(5-bromo-2-hy­droxy­benzyl­idene)benzohydrazide mono­hydrate

In t the title compound, C(14)H(12)BrN(3)O(2). H(2)O, the conformation of the C=N double bond in the hydrazide Schiff base mol-ecule is E. The dihedral angle between the benzene rings is 48.01 (11) °. An intra-molecular O-H⋯N hydrogen bond makes an S(6) ring motif. In the crystal, mol-ecules are linked through N-H⋯O (bifurcated acceptor) and O-H⋯O hydrogen bonds, forming two-dimensional network...

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Hexaaqua­magnesium bis­{4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]­benzene­sulfonate} dihydrate

In the title hydrated mol-ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry ) adopts a near regular MgO(6) octa-hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O-H⋯O and O-H⋯Br hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809035533